Brazing alloys

ABSTRACT

This invention relates to a silver based brazing alloy containing, apart from impurities, 40-50 percent by weight of silver, 20-33 percent by weight zinc, 12-40 percent by weight copper and optionally 0-5 percent by weight of tin. Brazing alloys which we have found particularly satisfactory are those containing A. 45 percent by weight silver, 25 percent by weight copper and 30 percent by weight zinc. B. 40 percent by weight silver, 30 percent by weight copper and 30 percent by weight zinc. C. 40 percent by weight silver, 30 percent by weight copper, 28 percent by weight zinc and 2 percent by weight tin, and 40 PERCENT BY WEIGHT SILVER, 27 PERCENT BY WEIGHT COPPER AND 33 PERCENT BY WEIGHT ZINC.

Unite States Patent 1 1 Sloboda et a1. v a

1 1 Jan. 28, 1975 BRAZING' ALLOYS [75] Inventors: Meczyslaw Herman Sloboda; John Sidney Hatswell, both of London, England [73] Assignee: Johnson Matthey & (20., Limited,

London, England 221 Filed: June 5,1913

21 Appl. No.: 367,226

[30] Foreign Application Priority Data June 7, 1972 Great Britain 26551/72 [52] [1.8. Ci. 75/134 C, 75/173 C [51] Int. Cl. C22c /00 [58] Field of Search 75/173 C, 134 C [56] References Cited UNITED STATES PATENTS 2,019,984 11/1935 Leach 75/173 C 2,189,640 2/1940 Powell 75/173 C 2,192,455 3/1940 Streicher 75/173 C 2,192,456 3/1940 Streicher 75/173 C 2,252,443 8/1941 Shipley 75/173 C Primary Examiner-L. Dewayne Rutledge Assistant Examiner-E. L. Weise Attorney, Agent, or Firm-Cushman, Darby & Cushman [5 7 1 ABSTRACT This invention relates to a silver based brazing alloy containing, apart from impurities, 4050 percent by weight of silver, -33 percent by weight zinc, 12-40 percent by weight copper and optionally 0-5 percent by weight of tin. Brazing alloys which we have found particularly satisfactory are those containing A, 45 percent by weight silver, percent by weight copper and percent by weight zinc.

B. percent by weight silver, 30 percent by weight copper and 30 percent by weight zinc.

C. 40 percent by weight silver, 30 percent by weight copper, 28 percent by weight zinc and 2 percent by weight tin, and

0 n y s ahtsi1 521P 911.Py' us copper and 33 percent by weight zinc.

5 Claims, No Drawings BRAZING ALLOYS This invention relates to a silver based brazing alloy.

One important property of a brazing alloy is its melting point. Generally speaking, overall brazing costs decrease proportionately with any reduction in the melting point of the brazing alloy used. Further, the lower the melting point of the brazing alloy the lesser the extent to which the mechanical properties of the metals to be joined are affected. Silver based brazing alloys containing copper, zinc and cadmium commonly have melting ranges below 650C. It is for this reason that silver-copper-zinc-cadmium brazing alloys with melting points down to 600C are widely used in industry.

However, if such alloys are incorrectly used they are liable to produce a toxic hazard owing to the presence of cadmium.

According to this invention a silver based alloy contains (apart from impurities) 40 to 50 percent by weight silver, 20 to 33 percent by weight zinc, 12 to 40 percent by weight copper and optionally to percent by weight tin.

Many of the silver based brazing alloys according to this invention possess the following properties:

TABLE 1 Alloy Composition Melting Range wt C Silver Ccgaper Zinc Tin Ag u Zn Sn The alloys listed in Table 1 exhibit cold work ability and may be fabricated in the wrought form. This is particularly convenient for the brazing techniques which are at present commonly used in industry.

Experimental data reproduced. in Tables 2 and 3 show that the mechanical properties of joints made in mild steel and 60/40 brass respectively compare favourably with those of similar joints made with one of the most widely used standard Ag-Cu-Zn-Cd alloys. They show also that a small departure from the range of compositions which come within the scope of the present invention produces a catastrophic decrease in the joint @sile strength andability to carry impact loads.

TABLE 2 Comparative data on certain mechanical properties of joints made in mild steel with the new brazing alloys. with a standard Ag-Cu-Zn-Cd alloy, and with an experimental Ag-Cu-Zn alloy which although of a similar composition to that of the alloys claimed is outside the scope of the present invention Brazing Alloy Joint Tensile Joint Shear Joint Resistance to Impact Bending Strength Strength tons/sq.inch tons/sq.inch Energy absorbed Location by the specimen. of

ft. lb. Fracture Ag-25Cu-30Zn 27.0 l L4 5.2 No Fracture 40Ag-30Cu-30Zn 29.4 11.3 5.0 do. 40Ag-30Cu-28Zn-2Sn 25.8 9.5 5.4 do. 40Ag-27Cu-33Zn 32.9 10.3 5.0 do. Ag-1S.5Cu-l9Cd-l5.5Zn 23.1 l 1.9 5.0 No fracture 40Ag-24Cu-36Zn Specimens 8.7 2.8 Specimens fractured fractured at during machining the joint interface Table 3 Comparative data on certain mechanical properties of joints made in /40 brass with the new brazing alloys with a standard Ag-Cu-Zn-Cd alloy Brazing Alloy Joint Tensile Joint Shear Joint Resistance to Impact Bending Strength Strength tons/sq.inch tons/sq.inch Energy absorbed Location by the specimen of ft.lb Fracture 45Ag-25Cu-30Zn l5.0 8.0 3.2 No fracture 40A g-30Cu-3 0Zn l 2.0 9.0 3.1 do. 40Ag-30Cu-28Zn-2Sn l9.5 5.5 3.5 do. 40Ag-27Cu-33Zn 16.0 8.4 3.2 .do. 7.1 3.2 do.

i. melting points not exceeding 720C;

.ii. ability to be produced in wrought forms (wire,

strip, foil);

iii. ability to produce strong and ductile joints with both ferrous and non-ferrous metals.

In addition the silver based brazing alloys according to this invention are non-toxic.

The melting ranges of four alloys according to the present invention which have been found to be particularly useful are given in Table l.

4 rities, 40 percent by weight silver, 30 percent by weight copper, 28 percent by weight zinc and 2 percent by weight tin.

5. An alloy consisting essentially of, apart from impurities, 40 percent by weight silver, 27 percent by weight copper and 33 percent by weight zinc. 

2. An alloy consisting essentially of, apart from impurities, 45 percent by weight silver, 25 percent by weight copper and 30 percent by weight zinc.
 3. An alloy consisting essentially of, apart from impurities, 40 percent by weight silver, 30 percent by weight copper and 30 percent by weight zinc.
 4. An alloy consisting essentially of, apart from impurities, 40 percent by weight silver, 30 percent by weight copper, 28 percent by weight zinc and 2 percent by weight tin.
 5. An alloy consisting essentially of, apart from impurities, 40 percent by weight silver, 27 percent by weight copper and 33 percent by weight zinc. 